To further verify the separation performance of the μGCC for methane and ethane, a temperature programmed method was used to test the light hydrocarbon mixture 2 (methane, ethane, propane and n-butane, wherein the concentration of methane is 20 % (v/v), the concentration of ethane, propane and n-butane is 0.2 % (v/v)), which is the …
In all cases, separation selectivity increased in the order of dipropylamine < di-sec-butylamine < CyNMe2 < TEPDA, i.e., TEPDA was best suited for the separation of hydrocarbons and their derivatives.
For the separation of oxygen and nitrogen from air, the two molecules only differ in size by about 0.18 angstroms (ten-billionths of a meter), he says. To make a filter …
involving nitrogen-containing switchable solvents are few. Accordingly, we make use of the variable ability of nitrogen-containing switchable solvents to separate different …
hydrocarbons, water vapor, carbon dioxide, carbon monoxide, nitrogen, condense at much higher temperatures than hydrogen. Hydrogen separation by partial condensation has been used mainly for recovery of hydrogen from petrochemical off-gases. These gases are compressed and cryogenically cooled in order to condense the hydrocarbon …
Nitrogen-containing switchable solvents for separation of hydrocarbons and their derivatives. Solvent extraction is commonly used to separate mixtures of hydrocarbons and their derivatives, and solvent choice is strongly influenced by the a nity to the target component, cost and safety. Nitrogen-. containing switchable solvents can switch from ...
The proprietary membranes are significantly more permeable to methane, ethane, and other hydrocarbons than to nitrogen. Gas containing 8% to 12% nitrogen is compressed and passed across a first set of membrane modules. The permeate, which contains 6% nitrogen, is sent to the pipeline; the nitrogen-rich residue gas is passed to a second set …
The upper column can have pure oxygen at the bottom, as oxygen has a higher boiling point than nitrogen. Comparison of Membrane Separation, Pressure Swing Adsorption, and Cryogenic Distillation Process (Cryogenic rectification) ... The hydrocarbons not removed from the air by the PPU unit accumulate in the liquid oxygen …
The new family of membrane materials, based on "hydrocarbon ladder" polymers, overcomes that tradeoff, providing both high permeability and extremely good selectivity, the researchers say. ... For the separation of oxygen and nitrogen from air, the two molecules only differ in size by about 0.18 angstroms (ten-billionths of a meter), he ...
Nitrogen production from air by membrane gas separation processes is a mature technology which is applied in numerous industrial sectors (chemical, food, aeronautics, space..). ... (hydrocarbons and solvent storage), or generation of inert atmospheres (e.g. non oxidizing) for chemicals or materials production, among others ...
Abstract. This work presents a theoretical investigation of the use of nanoporous carbon membranes for the separation of nitrogen from natural gas. A …
The past three decades have witnessed the fast growth and development of adsorptive purification and separation of hydrocarbons with a wide range of porous materials. We have summarized and discussed the recent developments of porous materials research for the separation of methane/nitrogen, ethene/ethane, propene/propane, and C 8 …
The model is first validated using the literature results for the separation of hydrogen from hydrocarbons mixture. The model is then applied to the nitrogen-hydrocarbons system. The membrane performance is evaluated in terms of nitrogen recovery, methane loss, nitrogen purity, as well as hydrocarbons compositions in both …
Nitrogen rejection is a challenging technical separation because of the similar molecular size of N 2 (∼0.36 nm) and CH 4 (∼0.38 nm). Several processes have been developed to treat natural gas to meet gas specifications.5 Many of these high-N 2 gas streams are diluted with low-N 2 gas to meet pipeline specifications. If this is not …
There is provided a process for the separation of a gaseous feed comprising a mixture of nitrogen, hydrocarbons and at least 0.005 mol % carbon dioxide, the process comprising: (i) cooling and at least partially condensing the gaseous feed, and (ii) separating in one or more stages the cooled and at least partially condensed gaseous feed into a …
Solvent extraction is commonly used to separate mixtures of hydrocarbons and their derivatives, and solvent choice is strongly influenced by the affinity to the target component, cost and safety. Nitrogen …
Hydrocarbon mixtures are generally difficult to separate using conventional solvents, e.g., benzene/cyclohexane mixtures can only be separated by extractive distillation in view of the similar volatilities of these hydrocarbons. 27–30 Li et al. showed that ILs can be used as entrainers to facilitate the separation of benzene and …
1. Introduction. The tail gases of the polyolefin plant, gas station exhaust gas [1], and purging vents of the fuel storage tanks [2] contain nitrogen and some hydrocarbons, e.g., ethylene, propylene, propane, and other heavy hydrocarbons (C ≥ 4).If these hydrocarbon-containing exhaust gases are sent to the flare for combustion …
The industrial use of cryogenic air separation units started more than 120 years ago. Cryogenic air separation processes produce pure nitrogen, oxygen, and argon, as well as other noble gases. In cryogenic air separation units, the produced amounts of nitrogen and oxygen vary between 200 and 40,000 Nm 3 / h and 1000 and 150,000 Nm …
This Minireview focuses on the developments of adsorbents for the separation and purification of hydrocarbons from, for example, methane/nitrogen, ethene/ethane, and propene/propane mixtures as well as for the separation of C 8 aromatics (i.e. xylene …
The separation of light hydrocarbons, including C 2 H 6 and C 3 H 8, is essential to natural gas upgrading.Meanwhile, N 2 removal from CH 4 is also crucial to concentrating low-quality coalbed methane, but the adsorption process is challenging because of the close kinetic diameter. This work reports two hydrogen-bonded metal …
the separation of nitrogen from the air, CO 2 from natural gas, and hydrog en from different refinery and petrochemical process streams. Many other applications use membranes on a smaller scale [1].
1. Introduction. Methane (CH 4), a typical non-polar molecule [1], has the highest hydrocarbon ratio and good chemical inertness.As the main component of natural gas (greater than85 vol%), it has a high burning heat value, up to 9510 kcal/Nm 3.Given that the products after burning are only H 2 O, CO 2 and a little NOx, methane has been …
March 24, 2022. Courtesy of the researchers. Industrial processes for chemical separations, including natural gas purification and the production of oxygen and nitrogen for medical …
A pressure-cycling process has been developed by which hydrogen can be separated from gas mixtures using palladium sponge as an absorbent. At a temperature of 200°C, with pressure cycling between 1 and 35 bar, and a cycle time of 20 seconds, hydrogen of 99.5 per cent purity can be obtained from 75 per cent hydrogen-25 per cent nitrogen mixtures …
Carbon hydrocarbon compounds, especially low-carbon hydrocarbons (C1–C3), are vital raw materials in the petrochemical industry, but their efficient separation has great challenges due to their similar molecular structures and properties. In contrast to traditional low-temperature distillation and absorption separation technologies, selective …
Polycyclic aromatic hydrocarbons are organic pollutants and composed of two or more fused aromatic rings of carbon and hydrogen atoms, which are primarily colorless, white, or pale yellow solid compounds ( Abdel-Shafy and Mansour, 2016; Suman et al., 2016 ). The molecular arrangements of aromatic rings in space can be linear, …
The invention provides a process and apparatus for the separation of a gaseous feed comprising a mixture of hydrocarbons and nitrogen gas, the process comprising the steps of: (i) cooling and at least partially condensing the gaseous feed; (ii) feeding the cooled and at least partially condensed feed from step (i) to a fractionation column comprising reboil …
Separation of air into oxygen and nitrogen is an important process, and this separation process has been applied in an industrial scale such as oxygen (O 2) enrichment from air (medical devices) and nitrogen (N 2) enrichment from air (used as protecting atmosphere for oxygen-sensitive compounds) (Jeazet et al. 2012).There are …
Research on porous materials for hydrocarbon separation and purification has experienced an explosive growth (Scheme 1 ). In this Minireview, we summarize the latest trends and related developments of hydrocarbon purification and separation ranging from methane/nitrogen, ethene/ethane, propene/propane separation to the separation …
This review summarizes the recent advances of using porous carbons as adsorbents for the separation of light hydrocarbons, including methane/nitrogen, methane/alkane, methane/carbon dioxide ...
Compared with 1 (carboxylate decorated NOTT-101), when nitrogen sites are inserted, the C 2 –C 3 hydrocarbon uptakes of NEM-4 can be significantly enhanced. Grand Canonical Monte Carlo and first-principles calculations reveal that not only the open Cu II sites but also the uncoordinated –COO − groups and the nitrogen sites play ...
Accordingly, we make use of the variable ability of nitrogen-containing switchable solvents to separate different hydrocarbons and their derivatives to design a …
nitrogen waste gas from the rectification process. → Removal of CO₂, water and hydrocarbons from the process air in periodically loaded/regenerated molecular sieve adsorbers. 3 Cold production and internal product compression → Cooling of process air in heat exchangers down to nearly liquefaction temperature by means of countercurrent ...
Metal-organic framework adsorbents are promising materials for gas separation and purification. Herein, the authors present a metal-organic framework that selectively captures CO2 over small ...
Abstract. Solvent extraction is commonly used to separate mixtures of hydrocarbons and their derivatives, and solvent choice is strongly influenced by the affinity to the target component, cost and safety. Nitrogen …
Separation and Purification Technology. Volume 283, 15 January 2022, 120206. Methane separation and capture from nitrogen rich gases by selective …
Membrane separation of Arabian light with DUCKY-9 removed roughly half of the sulfur and two-thirds of the nitrogen, as well as removed nickel, tin, and vanadium to below the detectable levels in ...
[Show full abstract] the feed gas, in at least one separation step, to produce a methane- and nitrogen-enriched first vapor phase and an ethane and higher hydrocarbon-enriched first liquid phase ...
